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Vehicle catalytic converters do not perform well at all until they reach a certain light-off temperature, which is well into the 400 to 600 F range. It takes a few minutes for the exhaust temperatures at the converter to reach that temperature, and so a sizable portion of vehicle emissions control is a function of getting the converter to temperature as quickly as possible.
I am not a chemist, and am not certain that the temperatures and available heat energy from a sodium acetate reaction or a similar one would be that significant in terms of improving catalytic converter warm-up times, but I'm really quite curious to find out.
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